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Activating Unreactive Substrates: The Role of Secondary Interactions
عنوان کتاب: Activating Unreactive Substrates: The Role of Secondary Interactions
مولف:
ناشر: Empty
زبان: English
سال: 2009
شابک: 9783527318230, 9783527625468
حجم فایل: 6.28 MB
نوع فایل: pdf
تعداد صفحات: 470
The use of secondary interactions for the activation of non-reactive substrates constitutes a new and modern approach in catalysis.
This first comprehensive treatment of this important research field covers the entire field and reveals the links between the various chemical disciplines. It thus adopts an interdisciplinary approach, making it of interest to the whole chemical community.
A must for organic, inorganic, catalytic and complex chemists, as well as those working with/on organometallics.Content:
Chapter 1 Chemistry of Metalated Container Molecules (pages 1–15): Berthold Kersting
Chapter 2 The Chemistry of Superbasic Guanidines (pages 17–37): Jorg Sundermeyer, Volker Raab, Ekatarina Gaoutchenova, Udo Garrelts, Nuri Abacilar and Klaus Harms
Chapter 3 Iron Complexes and Dioxygen Activation (pages 39–51): Thomas Nebe, Jing?Yuan Xu and Siegfried Schindler
Chapter 4 Tuning of Structures and Properties of Bispidine Complexes (pages 53–63): Peter Comba and Marion Kerscher
Chapter 5 Novel Phosphorus and Nitrogen Donor Ligands Bearing Secondary Functionalities for Applications in Homogeneous Catalysis (pages 65–88): Anna?Katharina Pleier, Yu Sun, Anett Schubert, Dirk Zabel, Claudia May, Andreas Reis, Gotthelf Wolmershauser and Werner R. Thiel
Chapter 6 Square?Pyramidal Coordinated Phosphine Iron Fragments: A Tale of the Unexpected (pages 89–102): Andreas Grohmann and Stephan Kohl
Chapter 7 Regioselective Catalytic Activity of Complexes with NH, NR?Substituted Heterocyclic Carbene Ligands (pages 103–122): Siegfried R. Waldvogel, Anke Spurg and Prof. Dr. F. Ekkehardt Hahn
Chapter 8 Functionalized Cycloheptatrienyl?Cyclopentadienyl Sandwich Complexes as Building Blocks in Metallo?Supramolecular Chemistry (pages 123–146): Matthias Tamm
Chapter 9 Monosaccharide Ligands in Organotitanium and Organozirconium Chemistry (pages 147–164): Peter Kitaev, Daniela Zeysing and Jurgen Heck
Chapter 10 Reactions of C?F Bonds with Titanocene and Zirconocene: From Secondary Interaction via Bond Cleavage to Catalysis (pages 165–182): Uwe Rosenthal, Vladimir V. Burlakov, Perdita Arndt, Anke Spannenberg, Ulrike Jager?Fiedler, Marcus Klahn and Marko Hapke
Chapter 11 Bisazines in the Coordination Sphere of Early Transition Metals (pages 183–207): Ruediger Beckhaus
Chapter 12 Bifunctional Molecular Systems with Pendant Bis(pentafluorophenyl)boryl Groups: From Intramolecular CH?Activation to Heterolytic Dihydrogen Splitting (pages 209–230): Michael Hill, Christoph Herrmann, Patrick Spies, Gerald Kehr, Klaus Bergander, Roland Frohlich and Gerhard Erker
Chapter 13 Ruthenium?Containing Polyoxotungstates: Structure and Redox Activity (pages 231–243): Ulrich Kortz
Chapter 14 From NO to Peroxide Activation by Model Iron(III) Complexes (pages 245–272): Alicja Franke, Natalya Hessenauer?Ilicheva, Joo?Eun Jee and Rudi van Eldik
Chapter 15 Synthetic Nitrogen Fixation with Molybdenum and Tungsten Phosphine Complexes: New Developments (pages 273–296): Gerald Stephan and Felix Tuczek
Chapter 16 Directed C?H Functionalizations (pages 297–312): Prof. Dr. Carsten Bolm
Chapter 17 Development of Novel Ruthenium and Iron Catalysts for Epoxidation with Hydrogen Peroxide (pages 313–337): Man Kin Tse, Bianca Bitterlich and Matthias Beller
Chapter 18 Pentacoordinating Bis(oxazoline) Ligands with Secondary Binding Sites (pages 339–348): Caroline A. Schall, Michael Seitz, Anja Kaiser and Oliver Reiser
Chapter 19 Flavin Photocatalysts with Substrate Binding Sites (pages 349–358): Harald Schmaderer, Jiri Svoboda and Burkhard Konig
Chapter 20 New Catalytic Cu?, Pd? and Stoichiometric Mg?, Zn?Mediated Bond Activations (pages 359–377): Tobias Thaler, Hongjun Ren, Nina Gommermann, Giuliano C. Clososki, Christoph J. Rohbogner, Stefan H. Wunderlich and Paul Knochel
Chapter 21 From Cobalt(II)?Activated Molecular Oxygen to Hydroxymethyl?Substituted Tetrahydrofurans (pages 379–396): Barbara Menendez Perez, Dominik Schuch and Jens Hartung
Chapter 22 Regiodivergent Epoxide Opening (pages 397–409): Andreas Gansauer, Florian Keller, Chun?An Fan and Peter Karbaum
Chapter 23 Supramolecular Containers: Host?Guest Chemistry and Reactivity (pages 411–425): Markus Albrecht
Chapter 24 Self?Assembly of Dinuclear Helical Metallosupramolecular Coordination Compounds (pages 427–446): Ulf Kiehne, Jens Bunzen and Arne Lutzen
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